View source for UV treatment / Solar disinfection (SODIS)

__NOTOC__ <small-title />
[[Image:Sodis_icon.png|right|80px]]
[[Image:Sodis.PNG|thumb|right|200px|Plastic bottles filled with contaminated water are placed in the sunlight. Photo: [http://www.sodis.ch/index_EN SODIS.]]]

Solar disinfection is a simple water treatment method using solar radiation (UV-A light and temperature) to destroy pathogenic bacteria and viruses present in the water. It can be used to disinfect small quantities of water with low turbidity. Most commonly, contaminated water is filled into transparent plastic bottles and exposed to full sunlight. The pathogens are destroyed during the exposure to the sun. Users determine the length of exposure based on the weather conditions. 

Other forms of batch treating and continuous treatment of water with sunlight are under development by various organizations.

====How it works====
Exposure to sunlight has been shown to deactivate diarrhea-causing organisms in polluted drinking water. EAWAG/SANDEC (2002) describes the three effects of solar radiation which are believed to contribute to the inactivation of pathogenic organisms:

* Ultraviolet-A (UV-A) radiation causes damage to DNA and kills living cells. 
* UV-A (wavelength 320-400nm) reacts with oxygen dissolved in the water and produces highly reactive forms of oxygen (oxygen free radicals and hydrogen peroxides), that are believed to also damage pathogens.
* Infrared radiation heats the water and causes pasteurization when the temperature is raised to 70-75 degrees Celsius. If the water temperatures raises above 50°C, the disinfection process is three times faster.

Many pathogens are not able to resist increased temperatures, nor do they have any protection mechanisms against UV radiation (EAWAG/SANDEC, 2002).

More pathogens are destroyed when they are exposed to both high temperature and UV-A light at the same time. A synergy of these two effects occurs for water temperatures above 50 degrees Celsius (Wegelin et al, 1994).

SODIS is more efficient in water with high levels of oxygen. Sunlight produces highly reactive forms of oxygen in the water. These reactive molecules also react with cell structures and kill pathogens (Kehoe et al, 2001).

The SODIS method (and other methods of household water treatment) can very effectively remove pathogenic contamination from drinking water. However, infectious diseases are also transmitted through other pathways such as direct person-to-person contact, food, or unhygienic living conditions. Lack of sanitation and hygiene practices exacerbate the problem. [http://www.sodis.ch/Text2002/T-Research.htm Studies] on the reduction of diarrhea among SODIS users show reduction values of 30-80%.

====History====
The fact that sunlight can kill micro-organisms has been known for centuries and has been scientifically established. 

The idea of solar water disinfection (SODIS) was presented by Professor Aftim Acra for the first time in a booklet published by UNICEF in 1984. SODIS has been promoted worldwide since 1991 when an interdisciplinary research team at EAWAG/SANDEC began laboratory and field tests to assess the potential of SODIS and to develop an effective, sustainable and low cost water treatment method. Solar disinfection is recommended by the World Health Oganization (WHO) as one viable option for drinking water treatment at household level.

===Suitable conditions ===
Basically the SODIS is suitable for batches of 1-2 litres per bottle. The system is not useful for treating large volumes of water, several are bottles needed for a large family. 

Bottles will melt and deform if the temperature reaches 65°C. 

The following issues should be considered for SODIS operation:

* '''Bottle material:''' Some glass or PVC materials may prevent ultraviolet light from reaching the water. Commercially available bottles made of  PET (Polyethylene terephthalate), such as the plastic bottles in which soft drink beverages are sold, are recommended. The handling is much more convenient in the case of PET bottles. Polycarbonate blocks all UVA and UVB rays, and therefore should not be used. Glass also blocks UV rays and therefore would be ineffective.

* '''Aging of plastic bottles:''' SODIS efficiency depends on the physical condition of the plastic bottles, with scratches and other signs of wear reducing the efficiency of SODIS. Heavily scratched or old, blind bottles should be replaced.
 
* '''Shape of Containers:''' the intensity of the UV radiation decreases rapidly with increasing water depth. Bottles used for SODIS should not exceed 10 cm in water depth. 1-2 litre volume PET bottles do not exceed this depth when they are horizontally placed in the sunlight (EAWAG/SANDEC, 2002). PET soft drink bottles are often easily available and thus most practical for the SODIS application.

* '''Oxygen''': Sunlight produces highly reactive forms of oxygen (oxygen free radicals and hydrogen peroxides) in the water. These reactive molecules contribute in the destruction process of the microorganisms. Under normal conditions (rivers, creeks, wells, ponds, tap) water contains sufficient oxygen (more than 3 mg oxygen per litre) and does not have to be aerated before the application of SODIS.

* For turbidity levels greater than 30 NTU, the water should first be filtered through a cloth or sedimented (Sommer et al, 1997).


{| border="1" cellpadding="5" cellspacing="0" align="center"
|-
! width="50%" style="background:#efefef;" | Advantages
! style="background:#f0f8ff;" | Disadvantages
|-
| valign="top" | - Very cheap, no capital costs except plastic bottle, no consumables required. <br>
- Independent from energy sources other than sunlight. <br>
- Treated water is protected from re-contamination in the bottles.<br>
- The taste of treated water is fresh, not stale or otherwise altered.<br>
- Convenient for storage and transportation. <br>
- SODIS has shown to significantly reduce diarrhoea 
| valign="top" | - Cannot be used on days with continuous rainfall.<br>
- Cannot be used to treat very turbid water (>30 NTU).<br>
- Bottles need to be replaced every 4-6 months.<br>
- Has a waiting period of 6-12 hours. <br> 
- Needs to be cooled before consumption <br>
- Does not remove suspended partices of dissolved compounds<br> 
|}


{{Potential_Treatment_Capacity_table
| highly=
- Bacteria<br>
- Viruses<br> 
- Protozoa<br>
- Helminths<br>
| somewhat= 
| not= 
- Turbidity<br>
- Chemicals<br>
- Taste, odour, colour
| process=
Disinfection<br> 
Safe Storage
| watcrit=Turbidity < 30 NTU
}}

The bottle can be used as a safe storage container. Requires suitable climate and weather conditions: the most favourable location is between latitudes 15° and 35° north/south; next most favourable location is between latitudes 15° north/south and the equator. PET bottles are abundant in urban areas, but may not be available in rural areas.

===Construction, operations and maintenance===

====Operation====
[[Image:Pictograms SODIS.jpg|800px]]

Transparent water bottles are filled with water from contaminated sources. To increase the oxygen dissolved in the water, bottles can be filled three quarters, then shaken for 20 seconds (with the cap on), then filled completely. Highly turbid water (turbidity higher than 30 NTU) must be filtered prior to exposure to the sunlight.

Filled bottles are then exposed to the sun. The treatment efficiency can be improved if the plastic bottles are placed on sunlight reflecting surfaces, such as corrugated aluminum or zinc roofs. This can increase the water temperature by about 5°C. 

Place the bottles horizontally on a roof or rack in the sun for the following times: 
* 6 hours in sunny weather 
* 6 hours for up to 50% cloudy weather<br>
* 2 consecutive days for 50-100% cloudy weather<br> 
* Do not use SODIS during days of continuous rainfall, use rainwater harvesting instead.

The efficiency of SODIS is dependent on the amount of sunlight available. The bottles must NOT be placed so that they are in shade for part of the day. The most favourable geographical regions for SODIS are located between latitudes 15oN and 35oN (as well as 15oS and 35oS). The majority of developing countries are located between latitudes 35oN and 35oS (EAWAG/SANDEC, 2002). If the water bottles are not exposed to sunlight for the proper length of time, the water may not be safe to drink and could cause illness. If the day is more than 50% cloudy, then it is necessary to expose the bottles for 2 days. If the temperature of the water is more than 50 degrees C, only 1 hour of exposure is required.

After treatment, the water can be consumed. The risk of re-contamination can be minimized if water is stored in the bottles. The water should be consumed directly from the bottle or poured into clean drinking cups. Re-filling and storage in other containers increases the risk of recontamination. Non-pathogenic organisms, such as algae, may grow in the conditions created in a SODIS bottle (EAWAG/SANDEC, 2002).

Users are unable to determine when sufficient disinfection has taken place. Users need to organize a rotation system to ensure they always have treated water and know which bottles have been treated.

====Manufacturing====
Materials and facilities needed are: 
* 1 or 2 litre clear plastic bottles (2 sets of 2 bottles per person, one set of bottles must be filled and placed on the roof each day, while the water in the other set is consumed)
* An alternative design using specially fabricated bags with a one-way valve integrating a temperature indicator has been proposed see YouTube video [http://www.youtube.com/watch?v=_k-SeaRj_QY]
* Accessible surface that receives full sunlight (e.g. roof, rack).

====Safety====
There has been some concern over the question whether plastic drinking containers can release chemicals or toxic components into water, a process possibly accelerated by heat. The Swiss Federal Laboratories for Materials Testing and Research have examined the diffusion of adipates and phthalates (DEHA and DEHP) from new and reused PET-bottles in the water during solar exposure. The levels of concentrations found in the water after a solar exposure of 17 hours in 60°C water were far below World Health Organization (WHO) guidelines for drinking water and in the same magnitude as the concentrations of phthalate and adipate generally found in high quality tap water.

Concerns about the general use of PET-bottles were also expressed after a report published by researchers from the University of Heidelberg on antimony being released from PET-bottles for soft drinks and mineral water stored over several months in supermarkets. However, the antimony concentrations found in the bottles are orders of magnitude below WHO [http://www.who.int/water_sanitation_health/dwq/chemicals/antimonysum.pdf] and national guidelines for antimony concentrations in drinking water. Furthermore, SODIS water is not stored over such extended periods in the bottles.

====Treatment Efficiency====
{{Treatment_Efficiency
|extra_field=-
|lab:bacteria=99.9 – 99.99% 
|lab:viruses=90 - 99.9% 
|lab:protozoa=90 - 99.9% <ref name=temp50>Depends on reaching a water temperature of 50 degrees.</ref> 
|lab:helminths= <ref name=temp50/>
|lab:turbidity=0
|lab:chemicals=0 
|lab:extra=
|field:bacteria=91.3-99.4% 
|field:viruses=not available
|field:protozoa=not available
|field:helminths=not available
|field:turbidity=0
|field:chemicals=0
|field:extra=-
}}

====Maintenance====
Bottles and caps should be cleaned on a regular basis.

====Estimated Lifespan====
Bottles become scratched or aged by sunlight and must be replaced periodically.

===Costs===
{{Treatment_Cost
|CapCost=US$ 0-5 (*) 
|OpCost=US$ 0
|ReplCost=US$ 2-5/year
|5yCost=US$ 10-25
|litreCost= US$ 0.003-0.008
}}
Note: Program, transportation and education costs are not included.
(*) PET bottles may be free or cost less than US$0.50

The cost of SODIS are very low, re-use of plastic bottles is common. According to a comparative [http://www.iwaponline.com/jwh/005/jwh0050599.htm study] on the cost-effectiveness of different household water treatment systems, SODIS is the least expensive method with an annual mean cost of US$0.63 per person.

===Field experiences===
Used by more than 1,000,000 in Asia, Africa and Latin America.

[[Image:SODIS map for Akvo.5.jpg|800px|Worldwide application of SODIS in projects coordinated by Eawag]]

The Swiss Federal Institute of Aquatic Science and Technology (Eawag), through the Department of Water and Sanitation in Developing Countries (Sandec), coordinates SODIS promotion projects in 33 countries including Bhutan, Bolivia, Burkina Faso, Cambodia, Cameroon, DR Congo, Ecuador, El Salvador, Ethiopia, Ghana, Guatemala, Guinea, Honduras, India, Indonesia, Kenya, Laos, Malawi, Mozambique, Nepal, Nicaragua, Pakistan, Perú, Philippines, Senegal, Sierra Leone, Sri Lanka, Togo, Uganda, Uzbekistan, Vietnam, Zambia, and Zimbabwe. Contact addresses and case studies of the projects coordinated by the Swiss Federal Institute of Aquatic Science and Technology (Eawag) are available at [http://www.sodis.ch/ sodis.ch].

===Manuals, videos and links===

====Video==== 

{|border="1" cellspacing="0" 
|-
|[http://www.youtube.com/watch?v=_k-SeaRj_QY Alternative design of a SODIS container]
|[http://www.youtube.com/watch?v=DSBz8f87ohQ&feature=channel_page Bolivia]
|[http://www.youtube.com/watch?v=5fAvX6sZXTM Kenya 1]
|[http://www.youtube.com/watch?v=jBsyH7aGUGg&feature=related Kenya 2]
|[http://www.youtube.com/watch?v=5s9fZ1Fi0nM&feature=channel_page Nepal pt.1]
|[http://www.youtube.com/watch?v=8KKanLz36bs&feature=channel_page Nepal pt.2]
|-
|[http://www.youtube.com/watch?v=g5o2tJ8gb0Q&feature=channel_page Nepal short]
|[http://www.youtube.com/watch?v=kh47lXnqzyI&feature=channel_page Pakistan]
|[http://www.youtube.com/watch?v=FnjO-y8-Crw Philippines]
|[http://www.youtube.com/watch?v=CXkgyaIreuc&feature=related Sierra Leone Sodis pt.1]
|[http://www.youtube.com/watch?v=nJiV0qKm1T8&amp;feature=related Sierra Leone Sodis pt.2]
|[http://www.youtube.com/watch?v=3A7I5S8k_ro South India]
|-
|[http://www.youtube.com/watch?v=gwivMQkAcfg&feature=channel_page Sri Lanka short]
|[http://www.youtube.com/watch?v=RN_c22teWME&feature=channel_page Sri Lanka Tsunami]
|[http://www.youtube.com/watch?v=LwJ9p5UHwhc&feature=channel_page Sri Lanka pt.1]
|[http://www.youtube.com/watch?v=5RXkT_7fdpQ&feature=channel Sri Lanka pt.2]
|[http://www.youtube.com/watch?v=jBsyH7aGUGg&feature=related Water ScH2Ool]
|}

====Links====

* [http://www.sodis.ch/methode/anwendung/ausbildungsmaterial/index_EN SODIS Training Material]. SODIS (short for Solar Water Disinfection) is an initiative of Eawag, the Swiss Federal Institute of Aquatic Sciences and Technology. 

* [http://enpho.org/ Drinking water quality information] from Environment and Public Health Organization (ENPHO). ENPHO at present runs a government accredited laboratory for environmental monitoring and analysis and is actively involved in promoting eco-friendly technologies such as SODIS, Ecosan toilets and waste water treatment through reed bed systems.

* [http://web.mit.edu/watsan/tech_hwts_chemical_kanchanarsenicfilter.html Kanchan Arsenic filter information from Massachusetts Institute of Technology (MIT)]

* [http://www.cdc.gov/safewater/publications_pages/options-sodis.pdf Household Water Treatment Options in Developing Countries: CDC Solar Disinfection (SODIS)]. Centers for Disease Control and Prevention. January 2008.

* [http://www.solvatten.se/ Solvatten] - a commercial product using SODIS principles. Solvatten is a household water treatment unit. The portable 11 liter container is a patented and scientifically proven Swedish invention. Put Solvatten in a sunny place, give it 2-6 hours and the water will be drinkable. An indicator shows when it is safe to drink. Solvatten can also be used as a solar water heater, providing hot water for cooking and hygiene.

===References===
<references/>

===Acknowledgements===
This article is based on a factsheet from [http://www.cawst.org/ Centre for Affordable Water and Sanitation Technology (CAWST)], which is gratefully acknowledged.

* EAWAG/SANDEC (2002). [http://www.sodis.ch/methode/anwendung/ausbildungsmaterial/dokumente_material/manual_e.pdf Solar Water Disinfection: A Guide for the Application of SODIS]. SANDEC Report No 06/02. 
* Saladin, M. (2002). SODIS in Nepal – Technical Aspects. EAWAG/SANDEC and ENPHO.
* Wegelin, M., Canonica, S., Mechsner, et al. (1994). [http://www.washdoc.info/docsearch/title/107952 Solar Water Disinfection: Scope of the Process and Analysis of Radiation Experiments], J Water SRT, Aqua Vol. 43, No. 4, pp 154-169.
* Wegelin, M., Canonica, S., Alder, A., et al. (2000) [http://www.environmental-expert.com/Files%5C5302%5Carticles%5C5905%5Ca2.pdf Does sunlight change the material and content of polyethylene terephthalate (PET) bottles?] or ([http://www.washdoc.info/docsearch/title/152914 alternative link]).  IWA Publishing, Journal of Water Supply: Research and Technology, Aqua No. 1.