Chlorine (NaDCC)
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What is a NaDCC?
Chlorine began to be widely used as a disinfectant in the early 1900’s. It revolutionized drinking water treatment and dramatically reduced the incidence of waterborne diseases. Chlorine remains the most widely used chemical for water disinfection in the United States. NaDCC, also known as sodium dichloroisocyanurate or sodium troclosene, is one form of chlorine used for disinfection. It is often used to treat water in emergencies, and is now widely available for household water treatment. NaDCC tablets are available with different chlorine content (e.g. 3.5 mg to 10 g) to treat from 1 to 3000 litres at a time. They are usually effervescent (meaning that escaping carbondioxide gas causes the tablets to dissolve quickly, with a 'fizz'), allowing the tablet to dissolve in less than 1 minute.
How Does It Remove Contamination?
When added to water, NaDCC releases hydrochloric acid which reacts through oxidization with microorganisms and kills them.
Three things can happen when chlorine is added to water:
- Some chlorine reacts through oxidization with organic matter and the pathogens in the water and kills them. This portion is called consumed chlorine.
- Some chlorine reacts with other organic matter and forms new chlorine compounds. This portion is called combined chlorine.
- Excess chlorine that is not consumed or combined remains in the water. This portion is called free residual chlorine (FRC). The FRC helps prevent recontamination of the treated water.
Operation
Each product should have its own instructions for correct dosing. In general, the user adds the correct sized tablet for the amount of water to be treated, following the product instructions. Then they agitate the container, and wait for the amount of time instructed on the package, normally 30 minutes (“contact time”). The water is then disinfected and ready to be used.
The effectiveness of chlorine is affected by turbidity, organic matter, temperature and pH. For high turbidity levels, the water should first be strained through a cloth or be sedimented before adding chlorine. These processes will remove some of the suspended particles and improve the reaction between the chlorine and pathogens.
Treatment efficiency
| Bacteria 1 | Viruses 2 | Protozoa3 | Helminths | |
|---|---|---|---|---|
| Resistance to Chlorine | low4 | moderate4 | high4 | not available |
Toxoplasma oocysts and cryptosporidium oocysts are highly resistant to chlorine disinfection 4. Chlorine alone should not be expected to inactivate these pathogens in drinking water.
Operating criteria
- Flow rate: Not applicable
- Batch volume: Unlimited
- Daily water supply: Unlimited
The manufacturer’s instructions for specific sodium hypochlorite products need to be followed. The required dose and contact time varies with water quality (e.g. turbidity, pH, temperature).
Use a 30 minute minimum contact time. If the pH is above 7.5, a higher Free Residual Clorine concentration of 0.6 mg/litre should be used and the contact time should be extended to 1 hour.
The contact time should be increased to 1 hour when the temperature is between 10˚ and 18˚C. It should be increased to two or more hours when the temperature falls below 10˚C.
Manufacturer’s instructions for specific NaDCC products need to be followed. The batch volume depends on size of the container used by the household.
Required dose and contact time varies with water quality (e.g. turbidity, pH, temperature). The minimum contact time to be needed is 30 minutes.
Robustness
Free residual chlorine protects against recontamination.
Most users cannot determine the dosing quantity themselves; proper use requires simple instructions from the manufacturer. Users often use less than the recommended dose to save money.
Chlorine requires a supply chain, market availability and regular purchase. It also requires quality control process to ensure product reliability. Sourcing suitable plastic containers to manufacture chlorine solutions can sometimes be a challenge.
Estimated lifespan
Chlorine deteriorates over time, especially in liquid form. Liquid chlorine products should be used within 3 months of being manufactured.
If stored in strip packs, the product has a shelf-life of five years. If stored in tubs, it has a three year shelf-life.
Manufacturing requirements
Worldwide producers
Medentech Ltd. manufactures Aquatabs for water disinfection, hospital surface infection control and general environmental disinfection.
Local production
NaDCC tablets cannot be produced locally, but they can be bought in bulk and packaged locally.
Materials and facilities
Tablets and packaging materials
Fabrication Facilities
Workshop space is required for packaging the tablets.
Labour
Anyone can be trained for light packaging work.
Hazards
NaDCC tablets do not contain hazardous chemicals, they are safe to handle and store. Manufacturer’s instructions should be followed.
Maintenance requirements
Products should be protected from exposure to temperature extremes or high humidity.
Cost
| Captial Cost | Operation Cost | Replacement Cost | Estimated 5 years Cost | Cost/liter treated |
|---|---|---|---|---|
| US$ 0 | US$ 3/year | US$ 0 | US$ 15 | US$ ~0.02 |
Note: Program, transportation and education costs are not included.
Other
Some NaDCC products claim that there is no bad odour or taste after use. Chlorine reacts with organic matter naturally present in water to form by-products such as trihalomethanes (THMs), which are potentially cancer-causing. Lantagne et al. (2008)5 indicate that THM levels produced during household chlorination may fall below World Health Organization (WHO) guideline values.
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External links
Acknowledgements
This article is based on a factsheet from Centre for Affordable Water and Sanitation Technology (CAWST), which is gratefully acknowledged.
Footnotes
- ↑ Bacteria include Burkholderia pseudomallei, Campylobacter jejuni, Escherichia coli, Salmonella typhi, Shigella dysenteriae, Shigella sonnei, Vibrio cholerae, Yersinia enterocolitica.
- ↑ Viruses include enteroviruses, adenoviruses, noroviruses, rotavirus.
- ↑ Protozoa includeEntamoeba histolytica, Giardia lamblia, Toxoplasma gondii, Cryptosporidium parvum.
- ↑ 4.0 4.1 4.2 4.3 CDC (2007)
- ↑ Lantagne et al. (2008)
References
- Clasen, T. and P. Edmondson (2006). Sodium dichloroisocyanurate (NaDCC) tablets as an alternative to sodium hypochlorite for the routine treatment of drinking water at the household level. International Journal of Hygiene and Environmental Health Volume 209, Issue 2, pp. 173-181.
- Clasen, T., Saed, T., Boisson, S., Edmondson, P., and O. Shipin. (2007). Household Water Treatment Using Sodium Dichloroisocyanurate (NaDCC) Tablets: A Randomized, Controlled Trial to Assess Microbiological Effectiveness in Bangladesh. Am. J. Trop. Med. Hyg., 76(1), 2007, pp. 187–192.
- Lantagne, D.S., Blount, B. C., Cardinali, F., and R. Quick, R (2008). Disinfection by-product formation and mitigation strategies in point-of-use chlorination of turbid and non-turbid waters in western Kenya. Journal of Water and Health, 06.1, 2008.
- Molla, N., (2007). Practical Household Use of the Aquatabs Disinfectant for Drinking Water Treatment in the Low-Income Urban Communities of Dhaka, Bangladesh. Thesis, Asia Institute of Technology, School of Environment, Resources and Development.